Product ID:SUPERCHEM 225 HC FIXER
MSDS Date:01/06/1988
FSC:6750
NIIN:00-155-6956
MSDS Number: BJYRV

CLAYTON CHEMICAL CO.

13310 FIGUEROA STREET
LOS ANGELES, CA 90061
US

Emergency Phone: 213-538-9530

Info Phone: 213-538-9530

Cage: 61803

CLAYTON CHEMICAL CO.

LOS ANGELES, CA 90061 US

Telephone: 310-538-9530/800-424-9300(CHEMTREC)

Cage: 61803

ACETIC ACID (SARA III)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 12%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT ESTABLISHED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION:IRRITATION, PULMONARY
EDEMA, AND CHEMICAL PNEUMONITIS. EYES:IRRITATION/BURNS.
SKIN:IRRITATION. VAPORS MAY CAUSE MUCOUS MEMBRANE IRRITATION.
INGESTION: MAY CAUSE BURNS OF THE ESOPHAGUS AND S TOMACH, ABDOMINAL
PAIN.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:IRRITATION OF EYES, SKIN, THROAT, COUGHING,
CHEST PAIN AND BREATHING DIFFICULTY.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, EYES AND LUNGS
MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES
HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:REMOVE
CONTAMINATED CLOTHING AND SHOES. WASH SKIN WITH SOAP AND WATER. GET
MEDICA L ATTENTION. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING
BY MOUTH IF UNCONSCIOUS. IMMEDIATELY GIVE ONE GLASS OF MILK OR
WATER. CALL A PHYSICIAN AT ONCE. NOTE: ALKALINE SOLUTION. TREAT
ACCORDINGLY.

Flash Point Method:CC
Flash Point:>109F,>43C
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:NEUTRALIZE WITH SODIUM BISULFATE. WIPE/SOAK UP
WITH PAPER TOWEL OR INERT ABSORBENT. PUT IN DISPOSAL CONTAINER.
REMOVE RESIDUE WITH LARGE AMOUNTS OF WATER BY FLUSHING TO AN
ACID-FREE SEWER.
Neutralizing Agent:SODIUM BISULFATE

Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN
NOT IN USE AND AWAY FROM ACIDS. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS. PROTECT CONTAINERS FROM DAMAGE.
Other Precautions:AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER
HANDLING. USE OF NON-ALKALINE TYPE HAND CLEANER REDUCES RISK OF
ALLERGIC SKIN REACTION.

Respiratory Protection:AN APPROPRIATE NIOSH-APPROVED RESPIRATOR FOR
ORGANIC VAPOR SHOULD BE WORN IF NEEDED.
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
Protective Gloves:NEOPRENE OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES.
LAUNDER CONTAMINATED CLOTHING PRIOR TO REUSE.

HCC:C2
Boiling Pt:=100.C, 212.F
Spec Gravity:1.15
pH:4.8
Evaporation Rate & Reference:<1 ( BU AC = 1 )
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT STRAW COLORED LIQUID WITH VINEGAR ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ALKALIES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:SULFUR DIOXIDE UNDER ACIDIC CONDITIONS
( PH <4 ), AND AMMONIA UNDER ALKALINE CONDITIONS ( PH >7 ).

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.